期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 87, 期 1, 页码 547-555出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.1c02559
关键词
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资金
- NSF of China [U2004192]
- Program for Science and Technology Innovation Talents in University of Henan Province [21HASTTT005]
- Science and Technology Research Project of Henan Province [202102310331]
- Key Scientific Research Project of Higher Education of Henan Province [19A150004]
- Nanyang Normal University [2019ZX006, 2018ZX001]
A new method for constructing six-membered cyclic phosphinamides without oxidants and transition metals has been developed, providing a new pathway for organic synthesis.
We developed an oxidant- and transition-metal-free approach to construct six-membered cyclic phosphinamides via an intramolecular electrochemical C-H phosphinamidation process. With (Bu4NBr)-Bu-n as the catalyst and electrolyte, cyclic phosphinamides bearing a variety of functional groups (22 examples) were readily accessed under mild conditions. Meanwhile, this protocol provided an alternative route to organic electroluminescent materials and P-N ligands.
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