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The reaction using gem-dizinc compounds: Structure and reactivity

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SOC SYNTHETIC ORGANIC CHEM JPN
DOI: 10.5059/yukigoseikyokaishi.58.108

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gem-dimetal; zinc; Witting type reaction; EXAFS; palladium; diketone; coupling reaction

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Reactions of gem-dimetallic reagents have attracted considerable attention as versatile reagents in organic synthesis. Consequently preparations of gem-dimetallic reagents have been extensively studied. Synthetic applications of the reagents have been focused on two reactions, regioselective olefination of carbonyl compounds and coupling with two different electrophilic building blocks.

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