期刊
SYNTHETIC METALS
卷 108, 期 3, 页码 245-247出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/S0379-6779(99)00137-X
关键词
polytriphenylamine; electrochemistry; polymerization; FTIR
In this paper the electrochemical synthesis of polytriphenylamine is shown for the first time. The electrochemical oxidation of triphenylamine (TPA) in nonpolar solvents leads to the formation of oligomers of TPA in solution and the formation of a polymer film with TPA as repeating unit. Cyclic voltammetry of these electrochemically produced TPA films is compared to that of chemically produced polytriphenylamine what demonstrates a similar electrochemical behaviour. From FTIR spectra of the polymer film it is concluded that the electrochemically formed polymer is more crosslinked than the chemically produced one. Therefore, it is a very stable redox polymer and a promising candidate for application in batteries, electrochromic displays, Sensors or organic electronic devices. (C) 2000 Published by Elsevier Science S.A. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据