期刊
ANALYTICA CHIMICA ACTA
卷 866, 期 -, 页码 69-74出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.aca.2015.01.039
关键词
Functionalized carbon dots; Electrochemical carbonization; One-pot synthesis; Fluorescent sensor; Mercury ions; Real water samples
资金
- National Natural Science Foundation of China [21375037, 21275051, 21475043]
- Scientific Research Fund of Hunan Provincial Science and Technology Department and Education Department [13JJ2020, 12A084]
- Doctoral Fund of Ministry of Education of China [20134306110006]
We propose a simple, economical, and one-pot method to synthesize water-soluble functionalized fluorescent carbon dots (C-Dots) through electrochemical carbonization of sodium citrate and urea. The as-prepared C-Dots have good photostability and exhibit a high quantum yield of 11.9%. The sizes of the C-Dots are mainly distributed in the range of 1.0-3.5 nm with an average size of 2.4 nm. It has been further used as a novel label-free sensing probe for selective detection of Hg2+ ions with detection limit as low as 3.3 nM. The detection linear range is 0.01-10 mu M. The as-prepared C-Dots are also successfully applied for the determination of Hg2+ in real water samples. (C) 2015 Elsevier B.V. All rights reserved.
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