Acid sites characterization of niobium phosphate catalysts and their activity in fructose dehydration to 5-hydroxymethyl-2-furaldehyde

The nature of different acid sites on the surface of various niobium-based catalysts has been spectroscopically investigated by means of FT-IR and UV-VIS techniques. Surface acidity has been further characterized by acetonitrile adsorption and subsequent FT-IR analysis. The catalytic activity of the different examined samples has been preliminarily tested in the fructose dehydration to 5-hydroxymethyl-2-furaldehyde, a reaction of relevant industrial interest. (C) 2000 Elsevier Science B.V. All rights reserved.