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The effect of fullerene doping on photoelectric conversion using titanyl phthalocyanine and a perylene pigment

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ELSEVIER SCIENCE BV
DOI: 10.1016/S0927-0248(99)00091-4

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organic photovoltaic device; titanyl phthalocyanine; N,N '-dimethyl-3,4 : 9,10-perylenebis; (dicarboximide); fullerene; doping

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The effect of fullerene (C(60)) doping on photoelectric conversion using titanyl phthalocyanine (TiOPc) and a perylene pigment, N, N'-dimethyl-3,4: 9,10-perylenebis(dicarboximide) (MPCI), was investigated. A new three-layer cell, ITO/MPCI/C(60)-doped TiOPc/TiOPc/Au, exhibited a higher quantum yield for charge-carrier photogeneration than a two-layer cell without the C(60)-doped TiOPc layer, ITO/MPCI/TiOPc/Au, upon irradiation with monochromatic light which TiOPc mainly absorbs. The three-layer cell showed a high conversion efficiency of 0.63 % for incident white light at an intensity of ca. 100 mW cm(-2). (C) 2000 Elsevier Science B.V. All rights reserved.

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