期刊
REACTIVE & FUNCTIONAL POLYMERS
卷 43, 期 1-2, 页码 139-143出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/S1381-5148(99)00078-4
关键词
oxidation of cyclohexene; polymer-bound-ruthenium complexes ruthenium; complexes; catalytic oxidation
Cyclohexene was oxidized to 2-cyclohexen-1-ol and 2-cyclohexen-1-one by atmospheric pressure of molecular oxygen in the presence of linear polystyrene-bound-2,2'-bipyridine-ruthenium complexes in the absence of solvent at 70+/-5 degrees C selectively. The alcohol/ketone molar ratio of the products can be adjusted by employing different additives or by varying the reaction pH. (C) 2000 Elsevier Science B.V. All rights reserved.
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