期刊
JOURNAL OF SOLID STATE CHEMISTRY
卷 151, 期 1, 页码 40-45出版社
ACADEMIC PRESS INC
DOI: 10.1006/jssc.2000.8619
关键词
layered perovskite niobate
The crystal structure of a layered perovskite niobate KCa2Nb3O10 was investigated through single-crystal X-ray analysis, The niobate crystallized in the orthorhombic system Cmcm with lattice constants of a = 3.8802(9) Angstrom, b = 29.508(6) Angstrom, c = 7.714(1) Angstrom. V = 883.2(2) Angstrom(3). The final refinement using the 908 independent reflections converged into R = 4.1%, and R-w = 4.7%, The structure of KCa2Nb3O10 was composed of triple-layered perovskite slabs, potassium ions being situated between the slabs, The adjacent perovskite slabs, stacking along the c asis, were mutually displaced with a displacement vector of (a) over right arrow/2. The potassium ions were coordinated by sis oxygen atoms to form two short and four long bonds, Apparent disordering was observed in the equatorial oxygen sites of the central niobium atoms in the triple perovskite slabs, (C) 2000 Academic Press.
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