期刊
JOURNAL OF CATALYSIS
卷 322, 期 -, 页码 104-108出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcat.2014.11.009
关键词
Gold catalyst; Hydrogel; Low critical solution temperature; A-3 coupling reaction; Heterogeneous catalysis; Polymer
资金
- National Research Foundation of Korea (NRF) - Korean Ministry of Education [2012R1A1A2001005, 2011-0023512]
- Korean Ministry of Education
- National Research Foundation of Korea [2012R1A1A2001005, 2011-0023512] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
Poly(NIPAM-co-4-VP), synthesized from N-isopropylacrylamide and 4-vinylpyridine with a 1:1 monomer ratio, exhibits a temperature-dependent phase transition in water with a low critical solution temperature (LCST) of 47 degrees C. Coordination of Au(III) with the polymer results in material with metal catalytic activity combined with the inverse solubility phenomenon of the polymer, which catalyzes the three-component coupling reaction of aldehydes, amines, and alkynes in water with excellent yields. The polymer not only functions as a supporter for Au(III) but also accelerates the catalysis by undergoing a coil-to-globule phase transition above the LCST. The catalyst is efficient, is stable in air, and tolerates a variety of substrates. Moreover, the recyclability of the catalyst makes it eco-friendly and economical to use. (C) 2014 Elsevier Inc. All rights reserved.
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