期刊
ELECTROCHEMISTRY COMMUNICATIONS
卷 2, 期 4, 页码 272-275出版社
ELSEVIER SCIENCE INC
DOI: 10.1016/S1388-2481(00)00022-9
关键词
electrochemical performance; catalytic oxidation; natural graphite; anode material; lithium ion battery
We demonstrate for the first time that the reversible capacity of common natural graphite modified by catalytic oxidation can serve as an anode material for lithium ion batteries with above-theoretical capacity of graphite. The enhancement of reversible lithium capacity from 251 to > 372 mAh g(-1) results from an increase in the numberer of micropores and nanometer channels, which are formed by both chemical and catalytic oxidation. Lithium can also form alloys with metals used as oxidation catalysts, and these alloys may also contribute to the enhancement of reversible lithium capacity. (C) 2000 Elsevier Science S.A. All rights reserved.
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