期刊
JOURNAL OF ORGANOMETALLIC CHEMISTRY
卷 598, 期 2, 页码 409-416出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/S0022-328X(00)00008-5
关键词
carbenes; fluoroalkylated carbenes; palladium complexes; X-ray structures
Fluoroalkylated N-heterocyclic carbene complexes of palladium have been synthesized from imidazolium salts and Pd(OAc)(2). The analogous carbene complexes bearing long alkyl chains have also been prepared. The formation of these carbene complexes proceeds via an intermediate binuclear species, which has been isolated. Complexes such as these may find applications in catalysis in supercritical CO2 (scCO(2)). (C) 2000 Elsevier Science S.A. All rights reserved.
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