期刊
PHYSICAL REVIEW LETTERS
卷 84, 期 17, 页码 3807-3810出版社
AMER PHYSICAL SOC
DOI: 10.1103/PhysRevLett.84.3807
关键词
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We study the effect of parity violation on the vibrational and rotational frequencies of CHBrClF We report the parity violating potentials as a function of reduced normal coordinates for all nine internal vibrational modes omega(1) to omega(9), using our new, accurate multiconfigurational-linear response (RPA and complete-active-space self-consistent field) approach. All modes wi show a strongly mode dependent relative shift Delta(pv)omega(i)/omega(i) (between 0.08 x 10(-16) and 13.3 x 10(-16), much smaller than all previous experimental tests could detect, including the most recent ones). The results are discussed in relation to other tests of parity violation.
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