4.7 Article

Ionic-Liquid Induced Changes in Cellulose Structure Associated with Enhanced Biomass Hydrolysis

期刊

BIOMACROMOLECULES
卷 12, 期 8, 页码 3091-3098

出版社

AMER CHEMICAL SOC
DOI: 10.1021/bm200736a

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资金

  1. U.S. Department of Energy, Basic Energy Sciences, Office of Science [DE-AC02-06CH11357]
  2. National Institutes of Health, National Center for Research Resources [RR007707]
  3. Oak Ridge National Laboratory
  4. Office of Biological and Environmental Research of the US Department of Energy
  5. SuGanit Systems [09-053]
  6. National Science Foundation [CBET 0933250]
  7. Directorate For Engineering
  8. Div Of Chem, Bioeng, Env, & Transp Sys [0959920, 0933250] Funding Source: National Science Foundation

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The effects of varying ionic liquid pretreatment parameters on various sources of lignocellulosic biomass have been studied using X-ray powder diffraction, X-ray fiber diffraction, and compositional analysis. Comparative enzymatic hydrolysis and sugar analysis were used to relate the observed changes in cellulose structure to biomass digestibility. In this study, the factor most clearly associated with enhanced biomass hydrolysis is the conversion of cellulose fibers from the cellulose I to the cellulose II crystal phase.

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