期刊
JOURNAL OF SOLID STATE ELECTROCHEMISTRY
卷 4, 期 5, 页码 243-266出版社
SPRINGER
DOI: 10.1007/s100080050202
关键词
stabilized hafnia; doped ceria; thoria; solid electrolyte; ionic conductivity
This review is focused on the analysis of experimental results on oxygen ion-conducting ceramic materials based on HfO2, CeO2, and ThO2, published in the former Soviet Union. In particular, the physicochemical and transport properties of fluorite-related oxides and the characteristics of electronic conduction in these solid electrolytes are briefly reviewed. Emphasis is given to electrocatalytic and electrochemical properties of cerium-containing oxides, which are promising materials for electrodes of electrochemical cells operating in reducing atmospheres, and mixed-conducting membranes. A comparative analysis of specific features of the solid-electrolyte ceramics based on hafnia, zirconia, ceria, and thoria is performed in order to reveal basic tendencies of oxygen ionic transport in fluorite-type oxides, and to identify the potential applicability of these materials in various high-temperature electrochemical devices.
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