期刊
ANALYTICA CHIMICA ACTA
卷 894, 期 -, 页码 7-19出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.aca.2015.08.053
关键词
Inductively coupled plasma - mass spectrometry; Tandem mass spectrometry; Reaction gas; Ultratrace analysis; Isotopic analysis
资金
- ACT-UR research project grant
- Ghent University (BOF-UGent)
- Spanish Ministry of Economy and Competitiveness [CTQ2012-33494]
- Aragon Government (Fondo Social Europeo)
This paper is intended as a tutorial review on the use of inductively coupled plasma - tandem mass spectrometry (ICP-MS/MS) for the interference-free quantitative determination and isotope ratio analysis of metals and metalloids in different sample types. Attention is devoted both to the instrumentation and to some specific tools and procedures available for advanced method development. Next to the more typical reaction gases, e.g., H-2, O-2 and NH3, also the use of promising alternative gases, such as CH3F, is covered, and the possible reaction pathways with those reactive gases are discussed. A variety of published applications relying on the use of ICP-MS/MS are described, to illustrate the added value of tandem mass spectrometry in (ultra) trace analysis. (C) 2015 Elsevier B.V. All rights reserved.
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