期刊
MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY
卷 74, 期 1-3, 页码 206-217出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/S0921-5107(99)00563-2
关键词
HREM; fullerene; carbon; BN; cluster
Carbon (C) and boron nitride (BN) fullerene materials (clusters, onions, intercalation, nanopolyhedra, nanotubes and nanocapsules) were synthesized by polymer pyrolysis, chemical reaction, are-melting and electron-beam irradiation. Atomic structure and formation mechanism were investigated by high-resolution electron microscopy, energy dispersive spectroscopy and electron energy-loss spectroscopy. Fullerene clusters and atomic clouds (atom hopping) were formed on the surface of the C and BN fullerne materials. They provided angular and spherical nanocage structures which consist of four-, five-, six-, and seven-membered ring bonding. Detection possibility of doping atoms in metallofullerene was discussed. included clusters showed some crystallographic relationship with {001} layers of C and BN fullerene materials, and a structure model was proposed. Photoluminescence and magnetic properties of C and BN nanocapsules were measured, which showed higher energy shift of luminescence and superparamagnetism. The present work indicates that the new C and BN fullerene materials with various atomic structure and properties can be produced by various synthesis methods, and a guideline for designing the C and BN fullerene materials is summarized. (C) 2000 Elsevier Science S.A. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据