期刊
SURFACE SCIENCE
卷 452, 期 1-3, 页码 1-8出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/S0039-6028(00)00291-0
关键词
angle resolved photoemission; electron energy loss spectroscopy (EELS); fullerenes; graphite; low index single crystal surfaces; surface structure, morphology, roughness, and topography
The intercalation of C-60 molecules underneath a monolayer of graphite (MG) adsorbed on Ni(111) has been investigated by means of high resolution electron energy loss spectroscopy (HREELS) and angle resolved photoemission (PE). Deposition of a thick layer of C-60 onto the MG/Ni(111) surface with subsequent annealing to 600-700 K leads to a partial intercalation of C-60 molecules underneath MG, i.e. formation of areas with intercalated C60 molecules and some initial MG/Ni(111) areas without intercalation. A number of interesting features in the HREEL and PE spectra can be ascribed to the areas with intercalated C60: Stiffening of the phonon modes up to values characteristic for pristine graphite, shift of the C-60 valence band states towards lower binding energies, and the appearance of a sharp structure close to the Fermi level. All these features can be explained assuming a modification (weakening) of the 'substrate-overlayer' interaction caused by the intercalation of C-60. (C) 2000 Elsevier Science B.V. All rights reserved.
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