期刊
HIGH PERFORMANCE POLYMERS
卷 12, 期 2, 页码 323-333出版社
IOP PUBLISHING LTD
DOI: 10.1088/0954-0083/12/2/307
关键词
-
FETI-5 (5000 g mol(-1)) is a relatively new adhesive and composite matrix that exhibits good processability and excellent properties. However in the fabrication of complex composite parts (i.e, skin stringer and support frames), better processability would offer distinct advantages, In an effort to improve the processability of PETI-5, a novel reactive additive was prepared and used to formulate blends. The reactive additive is a mixture of relatively simple phenylethynyl containing imides, As such, it exhibited solubility in a variety of solvents such as N-methyl-2-pyrrolidinone, a relatively low softening temperature (similar to 185 degrees C) and a low melt viscosity (similar to 0.1-0.3 Pa s at 250 degrees C). Neat resin blends prepared by physically mixing imide powders of the reactive additive and PETI-5 were thermally and rheologically characterized. Blends were also prepared by mixing NMP solutions of PETI-5 amide acid and the reactive additive (imide form). These solutions were subsequently used to prepare adhesive film and unidirectional carbon fibre tape using unsized IM7 fibre, The reactive additive/PETI-5 blends were used to fabricate titanium adhesive panels and composites under 0.54 MPa or less for 1 h at 350-371 degrees C. The effect of reactive additive content on the physical, rheological, adhesive and carbon fibre laminate properties was determined. One formulation exhibited a decrease in melt viscosity (i.e, improved processability) without effecting open hole compression, compression properties after impact or microcrack behaviour. The neat resin, adhesive and composite properties of these reactive additive/PETI-5 blends and their cured polymers will he discussed.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据