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Regiocontrol in an intramolecular Schmidt reaction:: Total synthesis of (+)-aspidospermidine

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卷 2, 期 11, 页码 1625-1627

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AMER CHEMICAL SOC
DOI: 10.1021/ol005913c

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  1. NIGMS NIH HHS [GM-07775] Funding Source: Medline

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[GRAPHICS] A total synthesis of (+)-aspidospermidine (1) is described, featuring an intramolecular Schmidt reaction as the key step. The effects of stereochemistry and protecting group status on the regia and chemoselectivity of this reaction were examined.

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