期刊
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
卷 157, 期 1-2, 页码 111-115出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/S1381-1169(00)00045-5
关键词
critical solution temperature; nonionic tensioactive phosphine ligand; organic monophase system; higher olefins; rhodium; hydroformylation
Application of the concept of critical solution temperature (CST) of nonionic tensioactive phosphine ligand P[p-C6H4O(CH2CH2O)(n)H](3) (PETPP) in the hydroformylation of higher olefins in organic monophase system is presented for the first time. The PETPP/Rh complex catalyst is insoluble: in organic solvent at room temperature (T < CST), on heating to the temperature T > CST, the catalyst would be soluble in organic solvent. Thus, the catalytic reaction would have taken place homogeneously at the reaction temperature (T > CST). When the reaction is completed, on cooling to the room temperature (T < CST), the catalyst would precipitate out from the organic solvent, and could be easily separated from the product and recycled efficiently. Hydroformylation of higher olefins catalyzed by PETPP/Rh complex in organic monophase system is investigated. Under the conditions of T= 130 degrees C, P = 4.0 MPa, the conversion of 1-dodecene and yield of the aldehyde are 95.8% and 93.7%, respectively. (C) 2000 Elsevier Science B.V. All rights reserved.
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