期刊
INORGANIC CHEMISTRY COMMUNICATIONS
卷 3, 期 7, 页码 361-367出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/S1387-7003(00)00099-X
关键词
carboxylato complexes; cluster compounds; crystal structures; manganese; N ligands; O ligands
Assembly of the tetranuclear oxomanganese(III) acetato cluster [Mn4O2(O2CMe)(7)(phen)(2)](BF4) from the dinuclear oxo-di(acetato)bridged manganese(III) species [Mn2O(O2CMe)(2)(H2O)(2)(phen)(2)](BF4)(2) . 3H(2)O in aqueous/acetic acid MeOH solution occurs via the new 'dimer of dimers' Mn-III complex [Mn2O(O2CMe)(3)(H2O)(phen)(2)](BF4) . MeOH possesing an unprecedent [Mn-4(mu-O)(2)(mu-O2Me)(4) (mu-(OH2O2CMe)-O-...)(2)] core. (C) 2000 Elsevier Science S.A. All rights reserved.
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