期刊
CHEMICAL PHYSICS LETTERS
卷 325, 期 4, 页码 411-419出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/S0009-2614(00)00701-6
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A series of mononuclear hexacoordinate iron(III) complexes, [Fe(L-5)(py)]BPh4, and binuclear hexacoordinate iron(III) complexes, [(L-5)Fe(mu(2)-bpy)Fe(L-5)](BPh4)(2), has been prepared and their magnetic properties were investigated; the pentadentate ligands were derivatives of L-5 = saldptn = N,N'-bis(2-hydroxybenzyliden)-1,7-diamino-4-azaheptane. Temperature variation of the effective magnetic moment for them shows that a spin transition from the low-spin to the high-spin state occurs. The magnetic data were fitted to an Ising-like model appropriate for the mono- and binuclear systems. (C) 2000 Elsevier Science B.V. All rights reserved.
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