期刊
TETRAHEDRON
卷 56, 期 34, 页码 6319-6330出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4020(00)00570-6
关键词
aminobisphosphonates; 2-aza-1,3-dienes; 2-aza-1,3,5-trienes; 2-phosphoryl pyridines
The synthesis and some reactions of imines derived from aminoalkylbisphosphonates and 2-aza-1,3-butadienes is described. Bisphosphonylalkylimino compounds are useful intermediates in the preparation of aminoalkylbisphosphonate derivatives by reduction of the imino linkage with sodium triacetoxyborohydride as well as in the synthesis of 2-aza-1,3-butadienes by an olefination reaction. The electrocyclization of phosphorylated 2-aza-1,3,5-trienes afforded substituted 2-phosphorylated pyridines. (C) 2000 Elsevier Science Ltd. All rights reserved.
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