4.6 Article

Percolation effects on adsorption-desorption hysteresis

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LANGMUIR
卷 16, 期 17, 页码 6999-7005

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AMER CHEMICAL SOC
DOI: 10.1021/la991465+

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In the present work we study how the adsorption-desorption hysteresis loop of a mesoporous-disordered medium represented by a three-dimensional dual site-bond model is affected by percolation for different kinds of site and bond distributions. The behavior of the threshold pressure for the evaporation process, as a function of the separation between the site and bond distributions and their dispersions, suggests a method to determine them from experimental adsorption-desorption hysteresis curves.

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