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Use of thallium(I) ethoxide in Suzuki cross coupling reactions

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ORGANIC LETTERS
卷 2, 期 17, 页码 2691-2694

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AMER CHEMICAL SOC
DOI: 10.1021/ol0062446

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  1. NCI NIH HHS [CA 76655] Funding Source: Medline
  2. NIGMS NIH HHS [GM 26782] Funding Source: Medline

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[GRAPHICS] Thallium(I) ethoxide promotes Suzuki cross couplings for a range of vinyl- and arylboronic acids with vinyl and aryl halide partners in good to excellent yields. This reagent offers distinct advantages over thallium(I) hydroxide in terms of commercial availability, stability, and ease of use.

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