期刊
ORGANIC LETTERS
卷 2, 期 17, 页码 2587-2589出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol0001214
关键词
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资金
- NIGMS NIH HHS [GM40171] Funding Source: Medline
[GRAPHICS] n-Pentenyl ortho esters (NPOEs) and n-pentenyl glycosides (NPGs) are interconvertible glycosyl donors which are activated by reaction with halonium ions. In a series of cyclic syn-1,3-diols, NPOEs have been found to specifically glycosylate the equatorial-OH while the NPG glycosylates predominantly, but not exclusively, the axial-OR. When the cyclic diol acceptor is presented with equivalent amounts of an NPOE and an NPG in a three component reaction, a single, double-glycosylation product is obtained, which conforms to the foregoing preferences, presenting evidence for site-selective glycosylation.
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