期刊
COORDINATION CHEMISTRY REVIEWS
卷 206, 期 -, 页码 263-283出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/S0010-8545(00)00267-8
关键词
lanthanide; reduction; steric; cyclopentadienyl; low valent; organometallic
For several decades the reductive chemistry of the lanthanide metals in soluble, fully characterized molecular species has focused primarily on just three elements: europium, ytterbium, and samarium. Recent developments suggest that the reductive chemistry of the lanthanides is likely to expand greatly beyond these three elements in the new millennium and will be a major area of advancement in lanthanide inorganic, organometallic, and coordination chemistry. This paper previews some possibilities in this held. (C) 2000 Elsevier Science S.A. All rights reserved.
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