期刊
PHYSICAL REVIEW E
卷 62, 期 4, 页码 4720-4724出版社
AMER PHYSICAL SOC
DOI: 10.1103/PhysRevE.62.4720
关键词
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Starting from the quantum description of isolated systems on the microscopic level we derive the two-generator formulation of nonequilibrium thermodynamics by means of the projection-operator technique. As a generalized canonical ensemble is employed, we obtain a convenient starting point for practical calculations in nonequilibrium thermodynamics; in particular also in the classical limit. All dynamical material properties are contained in a canonical nonequilibrium correlation. However, the generalized canonical approach is inappropriate for systems with large fluctuations; possible steps toward a suitable generalization for quantum systems are discussed.
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