期刊
CHEMICAL ENGINEERING SCIENCE
卷 55, 期 19, 页码 4175-4187出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0009-2509(00)00072-5
关键词
gas hydrates; surfactant; adsorption; natural gas; nucleation; energy
Micellar solutions were found to increase gas hydrate formation rate and alter formation mechanism for ethane and natural gas hydrates. A critical micellar concentration (CMC) of sodium dodecyl sulfate water solution was found to be 242 ppm at hydrate-forming conditions, where CMC was best determined by hydrate induction time. At surfactant concentrations above the CMC, hydrate formation rates in a quiescent system increased by a factor greater than 700. Above the CMC, hydrates initiated subsurface around the micelle-solubilized hydrocarbon gas. Developing hydrate particles migrated and adsorbed on the water-wet cell walls at the water-gas interface, where interstitial water-surfactant solution of the packed hydrate particles continued to react at the high rate. The development overcomes major limitations of future hydrate use in an industrial-scale natural gas storage process. (C) 2000 Elsevier Science Ltd. All rights reserved.
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