期刊
TETRAHEDRON
卷 56, 期 43, 页码 8561-8566出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4020(00)00798-5
关键词
ultrasound; heterogeneous oxidation; alkylarenes; alcohols; supported potassium permanganate
The ultrasound effect on the heterogeneous permanganate oxidation of benzyl alcohol and alkylarenes to the corresponding carbonyl compounds is examined. Application of ultrasonic irradiation leads to shorter reaction times as well as lower reaction temperatures. KMnO4 supported by copper sulfate pentahydrate in CH2Cl2 is possible to use for selective oxidation of benzyl alcohol to benzaldehyde. (C) 2000 Elsevier Science Ltd. All rights reserved.
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