期刊
TETRAHEDRON LETTERS
卷 41, 期 44, 页码 8473-8478出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(00)01486-6
关键词
asymmetric catalyst; asymmetric synthesis; solid-phase synthesis; Michael reaction; linked-BINOL
Polymer-supported linked-BINOL was synthesized to immobilize asymmetric catalysts with two BINOL units. The advantage of the polymer-supported linked-BINOL over randomly polymer-supported BINOL was confirmed by asymmetric Michael reaction. A novel polymer-supported La-Zn-linked-BINOL complex afforded the Michael adduct in good yield and moderate ee. (C) 2000 Elsevier Science Ltd. All rights reserved.
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