期刊
ANALYTICA CHIMICA ACTA
卷 888, 期 -, 页码 67-74出版社
ELSEVIER
DOI: 10.1016/j.aca.2015.07.028
关键词
Magnetic ionic liquids; Matrix solid-phase dispersion; Dispersive liquid-liquid microextraction; Magnetic separation; Oilseed
资金
- Special-funded Programme on National Key Scientific Instruments and Equipment Development of China [2012YQ090194]
- National Natural Science Foundation of China [21105037, 21207047, 21405057]
- Research Fund for the Doctoral Program of Higher Education [20110061120015]
A novel method was developed for the determination of six triazine herbicides from oilseeds by matrix solid-phase dispersion combined with magnetic ionic liquid dispersive liquid-liquid microextraction (MSPD-MIL-DLLME), followed by ultrafast liquid chromatography with ultraviolet detection (UFLC-UV). The MIL, 1-butyl-3-methylimidazolium tetrachloroferrate ([C(4)mim][FeCl4]), was used as the microextraction solvent to simplify the extraction procedure by magnetic separation. The effects of several important experimental parameters, including type of dispersant, ratio of sample to dispersant, type and volume of collected elution solvent, type and volume of MIL, were investigated. Using the present method, UFLC-UV gave the limits of detection (LODs) of 1.20-2.72 ng g(-1) and the limits of quantification (LOQs) of 3.99-9.06 ng g(-1) for triazine herbicides. The recoveries were ranged from 82.9 to 113.7% and the relative standard deviations (RSDs) were equal or lower than 7.7%. The present method is easy-to-use and effective for extraction of triazine herbicides from oilseeds and shows the potentials of practical applications in the treatment of the fatty solid samples. (C) 2015 Elsevier B.V. All rights reserved.
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