期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 65, 期 24, 页码 8224-8228出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo000820u
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Triphosgene was decomposed quantitatively to phosgene by chloride ion. The reaction course was monitored by LR spectroscopy (React-IR), showing that diphosgene was an intermediate. The methanolysis of triphosgene in deuterated chloroform, monitored by proton NMR spectroscopy, gave methyl chloroformate and methyl 1,1,1-trichloromethyl carbonate in about a 1:1 ratio, as primacy products. The reaction carried out in the presence of large excess of methanol (0.3 M, 30 equiv) was a pseudo-first-order process with a k(obs) of 1.0 x 10(-4) s(-1). Under the same conditions, values of k(obs) of 0.9 x 10(-3) s(-1) and 1.7 x 10(-2) s(-1) for the methanolysis of diphosgene and phosgene, respectively, were determined. The experimental data suggest that, under these conditions, the maximum concentration of phosgene during the methanolysis of triphosgene and diphosgene was lower than 1 x 10(-5) M. Methyl 1,1,1-trichloromethyl carbonate was synthesized and characterized also by the APCI-MS technique.
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