期刊
CHEMICAL PHYSICS LETTERS
卷 331, 期 2-4, 页码 154-162出版社
ELSEVIER
DOI: 10.1016/S0009-2614(00)01165-9
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Sub-picosecond, time-resolved absorption spectra of all-trans-neurosporene, both free in n-hexane solution and bound to the LH2 complex from Rhodobacter sphaeroides G1C, were recorded and analyzed by singular-value decomposition followed by global fitting using a sequential model. The former experiment identified the 1B(u)(+)--> 1B(u)(-) --> 2A(g)(-) internal conversion, whereas the latter experiment identified a transformation of 1B(u)(+) --> 2A(g)(-) --> T-1(l(3)B(u)(+)). Excitation to the 1B(u)(+)(0) or 1B(u)(+)(1) vibronic level resulted in enhancement of stimulated emission from the particular level. showing that vibrational relaxation in the 1B(u)(+) state has a time constant comparable to, or larger than, that of electronic relaxation. (C) 2000 Elsevier Science B.V. All rights reserved.
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