期刊
ACTA MATERIALIA
卷 48, 期 20, 页码 4783-4790出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S1359-6454(00)00277-9
关键词
alloys; kinetics; SANS and DSC; magnetic properties
The kinetics of copper clustering and primary crystallization of FINEMET type alloys with the compositions Fe74.5-xSi13.5B9Nb3Cux and Fe77Si11B9Nb3-xCux have been studied by small-angle neutron scattering (SANS) and high-sensitivity differential scanning calorimetry (DSC) in order to explain the different optimized Cu contents, x, for obtaining the highest permeability in these two alloys. SANS results have shown that the alloys with the optimized Cu contents have the finest nanocrystalline microstructures. Kinetic analyses of Cu clustering prior to primary crystallization have shown that the number density of Cu clusters becomes highest at the crystallization stage of alpha -Fe primary crystals in the alloy containing an optimized amount of Cu. (C) 2000 Acta Metallurgica Inc. Published by Elsevier Science Ltd. All rights reserved.
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