4.8 Article

Elasticity of MgO and a primary pressure scale to 55 GPa

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NATL ACAD SCIENCES
DOI: 10.1073/pnas.240466697

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We have studied the elasticity and pressure-density equation of state of MgO in diamond cells to 55 GPa and have doubted the previous pressure limit of accurate elasticity determinations for crystals. Integrating single-crystal velocity data from Brillouin scattering measurements and density data from polycrystalline x-ray diffraction, we obtained the three principal elastic tensor elements (C-11, C-12, and C-44) and various secondary elasticity parameters, including single-crystal elastic anisotropy, Cauchy relation, aggregate sound velocities, and Poisson's ratio, as functions of pressure. The present study also provides a direct determination of pressure without recourse to any prior pressure standard, thus creating a primary pressure scale. The commonly used ruby fluorescence pressure scale has thus been improved to 1% accuracy by the new MgO scale.

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