期刊
APPLIED PHYSICS LETTERS
卷 77, 期 24, 页码 3938-3940出版社
AMER INST PHYSICS
DOI: 10.1063/1.1332820
关键词
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Powder x-ray diffraction has been used to study the structural properties of multilayered heterostructures grown by organic molecular-beam deposition and based on the molecular materials H2Pc, perylene-3, 4, 9, 10-tetracarboxylic dianhydride (PTCDA) and Alq(3). Structural templating has been observed for multilayers of PTCDA and H2Pc, with the first layer completely disrupting the structure of subsequent layers. H2Pc adopts a new structure when deposited on PTCDA, in which the molecular plane is oriented parallel to the substrate and this configuration is retained for film thicknesses > 380 nm. The templating effect extends through molecular thin-film structures involving several different layers, but is attenuated by insertion of an amorphous layer such as Alq(3). (C) 2000 American Institute of Physics. [S0003-6951(00)02251-8].
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