4.7 Article

Study on the thermal behaviour and flammability of the modified polyacrylonitrile fibers

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JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
卷 63, 期 2, 页码 501-506

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SPRINGER
DOI: 10.1023/A:1010181618305

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apparent activation energy; char residue; metal-containing PAN fibers; pyrolysis; thermal analysis; thermal degradation

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The effects of some kinds of metal ions used as chemical modifications on the thermal properties of the modified polyacrylonitrile (PAN) fibers were studied by DTA, TG, GC and cone calorimetry. The apparent activation energies for the decomposition of the unmodified and modified PAN fibers were determined using Kissinger equation and Broido equation.

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