期刊
TETRAHEDRON LETTERS
卷 42, 期 2, 页码 327-329出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(00)01940-7
关键词
enones; mechanisms; thioethers; zinc and compounds
Systematic changes in the substitution pattern of linear enones ((RCOCH)-C-1=CHR2) helps identify the reactive conformation (s-trans versus s-cis) of the enone in copper-catalysed asymmetric 1,4-ZnEt2 addition. Pointers to the binding mode of the Lewis Acid (syn or anti to the 'ene' function) are also gathered. Enantioselectivities of up to 79% have been realised in these reactions. (C) 2000 Elsevier Science Ltd. All rights reserved.
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