期刊
TETRAHEDRON LETTERS
卷 42, 期 3, 页码 445-448出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(00)01979-1
关键词
electrochemistry; oxidation; alcohols; enantioselective
N-Oxyl-mediated electrooxidation of alcohols was performed in an aqueous silica gel disperse system. The newly devised electrolysis system offers an organic solvent-free and operationally simple procedure for oxidation of alcohols and could be successfully applied to kinetic resolution of sec-alcohol as well as enantioselective oxidation of meso-1,4-diol affording optically active gamma -lactone. (C) 2001 Elsevier Science Ltd. All rights reserved.
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