期刊
TETRAHEDRON
卷 57, 期 5, 页码 835-843出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4020(00)01047-4
关键词
allylation; catalysis; Lewis acids; Schiff bases
In this paper, we present the data obtained from kinetic analysis and from NLE study in the [Cr(Salen)] catalysed addition of allyl halides to aldehydes. The results show the key role played by weak Lewis acids in the catalytic system. Weak Lewis acids such as manganese salts and the [Cr(Salen)X] complex drive the stereochemistry of the reaction toward a high level of diastero- and enantioselectivity. Therefore, the Lewis acids and their properties must be taken into account in the rational design of metallo-Salen mediated processes. (C) 2001 Elsevier Science Ltd. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据