期刊
CORROSION SCIENCE
卷 43, 期 2, 页码 243-254出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0010-938X(00)00049-4
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In the third part of this series of papers a kinetic analysis of the experimental data shown in Parts 1 and 2 are presented. Further experiments demonstrate the strong influence of CO2 on the delamination kinetics. For CO2 concentrations lower than 1 vol% the rate of delamination is reduced drastically without changing the reaction, between 1 vol% and 2 vol% the overall delamination rate is no longer controlled by diffusion of irons but by a charge transfer controlled O-2-reduction. The results are interpreted by thin zinc carbonate layers formed at the interface, which inhibit the rate of the ETR. (C) 2001 Elsevier Science Ltd. All rights reserved.
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