期刊
CHEMICAL ENGINEERING SCIENCE
卷 56, 期 4, 页码 1551-1559出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0009-2509(00)00382-1
关键词
integrated process; ion-exchange; catalytic hydrogenation; nitrate removal; Pd-Cu bimetallics; drinking water purification; batch-recycle reactor
A nitrate removal process that drastically reduces salt consumption and waste discharge has been developed on a bench scale. Nitrate is removed by chloride ion-exchange, and the: strong-base anion resin is completely regenerated at mild reaction conditions (i.e., ambient temperature, atmospheric pressure) in a closed circuit containing a single-flow fixed-bed reactor packed with a Pd-Cu/gamma -Al2O3 catalyst. The combined treatment system avoids direct contact between the denitrification reactor and the water to be treated, and minimizes operational problems associated with each separate technique. No dissolution of Pd and Cu metallic phases was observed at the given operating conditions. (C) 2001 Elsevier Science Ltd. All rights reserved.
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