A multilevel relaxation model has been developed to describe the dynamic behavior of a single-domain particle from blocked through to superparamagnetic. When combined with an accurate expression for the relaxation time and a log-normal particle size distribution, this model successfully describes the Mossbauer spectra of real fine particle systems at all temperatures of interest, and yields consistent values for anisotropy and blocking temperature. Spectra of two Fe3O4 ferrofluids and a polysaccharide iron complex have been fitted. Blocking temperatures (T-B) determined with our model agree with those extrapolated from frequency dependent chi (ac) data. Anisotropy energies (K) are in the range of 1-3 x 10(4) J/m(3) and superparamagnetic relaxation times are similar to 10(-8) s. Interparticle interactions are shown to reduce both K and T-B.
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