期刊
TETRAHEDRON LETTERS
卷 42, 期 8, 页码 1483-1485出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(00)02290-5
关键词
fatty acid amides; N-17-hydroxy-linolenoyl-L-glutamine; 1-phenyl-ethylisocyanate; stereochemistry
The absolute configuration of the hydroxylinolenoyl moiety of volicitin (17-hydroxylinolenoyl-L-glutamine) 1a/b from four lepidopteran larvae was determined by methanolysis and derivatisation of the resulting ester with (1R)-1 -phenyl-ethylisocyanate 3. The absolute configuration of the resulting (1'R)-17-(1'-phenyl-ethylcarbamoyloxy)-methyl linolenoates 4a/b followed from GLC comparison with synthetic references. Natural volicitin 1 from caterpillars of Spodoptera exigua, S. frugiperda, S. littoralis and Heliothis virescens (Noctuidae) exhibits a high ee (92-96%) and has a 17S configuration. (C) 2001 Elsevier Science Ltd. All rights reserved.
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