期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 66, 期 4, 页码 1380-1386出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo001514j
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资金
- NIGMS NIH HHS [GM56677] Funding Source: Medline
This paper describes a formal total synthesis of the marine ladder toxin hemibrevetoxin B from Danishefsky's dienes. This approach couples the generation of C-glycosides from cyclic enol ethers with metathesis or acid-mediated annulation reactions. The result is a highly efficient synthesis of the tetracyclic ring system of hemibrevetoxin B.
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