4.6 Article

A colorimetric method of analysis for trace amounts of hydrogen peroxide with the use of the nano-properties of molybdenum disulfide

期刊

ANALYST
卷 140, 期 4, 页码 1119-1126

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4an01950d

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资金

  1. National Natural Science Foundation of China [NSFC-21365014, NSFC-21305061]
  2. Natural Science Foundation of Jiangxi Province [20132BAB213011, 20132BAB203011]
  3. Education Department Science Foundation of Jiangxi Province [GJJ13026]
  4. State Key Laboratory of Food Science and Technology of Nanchang University [SKLF-ZZA201302, SKLF-ZZB201303]

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Molybdenum disulfide (MoS2) is an emerging material with some unique physical and electronic properties somewhat comparable to those of graphene. It was prepared with the use of a simple hydrothermal process, and has a layered structure similar to that of graphene. Also, it has a peroxidase-like catalytic activity and is able to catalyze the oxidation of the colorless peroxidase substrate, 3,3', 5,5'-tetramethylbenzidine (TMB), in the presence of H2O2 to produce a blue product. This reaction used MoS2 as a useful peroxidase, which involved a colorimetric method for trace analysis of H2O2 in water, e. g. lake waters. This method is uncomplicated, inexpensive and highly sensitive for H2O2 in the 0.125-1.75 mu M range (LOD: 0.08 mu M). It is also quite stable in the presence of many common inorganic and organic potentially interfering compounds, e. g. metal ions as well as amino acids and sugars.

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