期刊
JOURNAL OF SYNCHROTRON RADIATION
卷 8, 期 -, 页码 713-715出版社
WILEY-BLACKWELL
DOI: 10.1107/S0909049500020884
关键词
XANES; binuclear copper( II) dithiocarbamate; chemical shift; principal absorption maximum
X-ray K-absorption near edge studies have been carried out onthe binuclear copper (II) dithiocarbamate (dtc) complexes having the following general structure: [GRAPHICS] where R = me (methyl); et (ethyl); npr (normal propyl); chx (cyclohexane) It has been found that the chemical shift values are higher in the chlorine adducts as compared to the values of chemical shift reported by us in an earlier work for the parent complexes, showing that the chlorine adducts are more ionic. The observed splitting of the principal absorption maximum (1s-->4p) in the chlorine adducts has been explained in terms of the splitting of the metal 4p orbital degeneracy.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据