期刊
TETRAHEDRON
卷 57, 期 10, 页码 1961-1972出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4020(01)00033-3
关键词
alkylation; 1-amino-3,4-dihydropyridin-2-ones; 1-aminopyrroles; 1-aminopyrrol-2-ones; hydrazones; phosphine oxides; phosphonates
Functionalized hydrazones derived from phosphine oxides or phosphonates were obtained from azaenolates of hydrazones and alkyl halides. The regioselectivity of alkylation of a-phosphorylated hydrazones can be controlled by phosphorus moiety. alpha -Alkylated compounds were used for the synthesis of heterocycles such as 1-aminopyrrol-2-ones, 1-amino-3,4-dihydropyridin-2-ones and 1-amino-pyrroles containing phosphinyl or phosphoryl substituents. (C) 2001 Elsevier Science Ltd. All rights reserved.
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