4.4 Article

Transition-metal complex-catalyzed reduction of amides with hydrosilanes: a facile transformation of amides to amines

期刊

TETRAHEDRON LETTERS
卷 42, 期 10, 页码 1945-1947

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PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(01)00039-9

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transition metals; catalysts; reduction; silicon and compounds; amides; amines

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The reaction of amides with hydrosilanes is catalyzed by a variety of transition-metal complexes in the presence or absence of halides and amines as co-catalysts to afford the corresponding amines in good yields. (C) 2001 Elsevier Science Ltd. All rights reserved.

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